乔换灵;强西怀;崔璐;许伟;李成涛;
QIAO Huanling;QIANG Xihuai;CUI Lu;XU Wei;LI Chengtao;College of Bioresources Chemical and Materials Engineering,Shaanxi University of Science & Technology;National Demonstration Center for Experimental Light Chemistry Engineering Education,Shaanxi University of Science & Technology;School of Environmental Science and Engineering, Shaanxi University of Science & Technology;

• 1:陕西科技大学轻工科学与工程学院
• 2:轻化工程国家级实验教学示范中心(陕西科技大学)
• 3:陕西科技大学环境科学与工程学院

摘要(Abstract)：

从无铬鞣制的必要性出发,对近年来各界学者对无铬鞣剂及其鞣制方法领域所做出的研究进行了综述,主要介绍了非铬金属鞣剂、有机鞣剂和新型无铬鞣剂的开发进展情况及其基本的鞣革性能,对一些产品的实际应用现状进行了分析,并指出鞣革性能、材料配伍性、生物降解性、产品稳定性和市场接纳性是开发无铬鞣剂重点考虑的问题。
The recent researches on chrome-free tanning agents and their tanning methods were reviewed from the necessity of chrome-free tanning.The development and basic tanning properties of non-chrome metal tanning agents,organic tanning agents and new chrome-free tanning agents were mainly introduced,and the actual application status of some products was analyzed.It is pointed out that tanning performance,material compatibility,biodegradability,product stability and market acceptance are the key considerations in the chrome-free tanning agents development.

关键词(KeyWords)： 非铬金属鞣剂;有机鞣剂;无铬鞣剂;无铬鞣制;皮革
non-chrome metal tanning agent;organic tanning agent;chrome-free tanning agent;chrome-free tanning;leather

Abstract:

Keywords:

基金项目(Foundation): 国家重点研发计划项目(2017YFB0308500);; 陕西科技大学创新科研团队(TD12-04);陕西科技大学研究生创新基金

作者(Author): 乔换灵;强西怀;崔璐;许伟;李成涛;
QIAO Huanling;QIANG Xihuai;CUI Lu;XU Wei;LI Chengtao;College of Bioresources Chemical and Materials Engineering,Shaanxi University of Science & Technology;National Demonstration Center for Experimental Light Chemistry Engineering Education,Shaanxi University of Science & Technology;School of Environmental Science and Engineering, Shaanxi University of Science & Technology;

Email:

参考文献(References)：

• [1] Shi J,Puig R,Sang J,et al.A comprehensive evaluation of physical and environmental performances for wet-white leather manufacture [J].Journal of Cleaner Production,2016,139:1 512-1 519.
• [2] Saravanabhavan S,Palanisamy T,Thirumalachari R.Natural leathers from natural materials:Progressing toward a new arena in leather processing [J].Environ.Sci.Technol.,2004,38:871-879.
• [3] Dima W N,Rashed M Al-Sa'ed,Maarten A S.Reducing the environmental impact of the unhairing deliming process in the leather tanning industry [J].Journal of Cleaner Production,2006,14:65-74.
• [4] 袁绪政,王学川.高吸收清洁化铬鞣技术[J].皮革与化工,2009,26(1):20-23.Yuan X Z,Wang X C.Clean chrome tanning technology of high exhaustion[J].Leather and Chemicals,2009,26(1):20-23.
• [5] Lakshmi M,Rajat B M.A cleaner production method for the synthesis of bronopol-A bactericide that is useful in leather making[J].Journal of Cleaner Production,2006,14:536-538.
• [6] Hansen M,Johansen J,Menne T.Chromium allergy:Signi fī cance of both Cr(Ⅲ) and Cr(Ⅵ) [J].Contact Dermat,2003,49:206-212.
• [7] Parthasarathi K.Cleaner processing options to combat the pollution problems in leather processing[J].Chemical Business,1998,12:7.
• [8] Liu M H,Zhang H,Zhang X S,et al.Removal and recovery of chromium(Ⅲ) from aqueous solutions by a spherical cellulose adsorbent[J].Water Environ Res,2001,73:322-328.
• [9] Lee T,Lim H,Lee Y,et al.Use of waste iron metal for removal of Cr(Ⅵ) from water[J].Chemosphere,2003,53:479-485.
• [10] Alguacil F A,Alonso M,Lozano L J.Chromium (Ⅲ) recovery fromwaste acid solution by ion exchange processing using Amberlite IR-120 resin:Batch and continuous ion exchange modeling[J].Chemosphere,2004,57:789-793.
• [11] Liu M H,Zhou H L,Zhang H Y.Recovery of chromium (Ⅲ)from chrome tanning waste water by precipitation and adsorption process[J].J Soc Leather Technol Chem.,2006,90:183.
• [12] María V,Galiana A,José A,et al.Reducing sulfates concentration in the tannery effluent by applying pollution prevention techniques and nanofiltration[J].Journal of Cleaner Production,2011,19:91-98.
• [13] 张婧.淀粉改性丙烯酰胺与铝配合物鞣剂的合成及性能研究[D].西安:陕西科技大学,2017.Zhang J.Study on synthesis and properties of starch modified acrylamide and aluminum complex tanning agent[D].Xi’an:Shaanxi University of Science & Technology,2017.
• [14] 张婧,李运涛,苏秀霞.淀粉改性丙烯酰胺与铝配合物鞣剂的合成[J].中国皮革,2016,45(8):25-31.Zhang J,Li Y T,Su X X.Synthesis starch modified acrylamide and aluminum complex tanning agent[J].China Leather,2016,45(8):25-31.
• [15] 方玉婷,张金伟,宁国强,等.微波辐照对硫酸锆水解和锆鞣皮粉热稳定性的影响[J].皮革科学与工程,2017,27(3):12-16.Fang Y T,Zhang J W,Ning G Q,et al.Effects of microwave irradiation on hydrolysis of Zirconium sulfate and thermal stability of Zirconium tanned powder[J].Leather Science and Engineering,2017,27(3):12-16.
• [16] Yu Y,Wang Y N,Ding W,et al.Preparation of highly-oxidized starch using hydrogen peroxide and its application as a novel ligand for zirconium tanning of leather[J].Carbohydrate Polymers,2017:174.
• [17] 许冰斌,贺贤贤,陈华,等.无铬多金属鞣剂ZAT及加脂的影响[J].皮革与化工,2017,34(2):21-25.Xu B B,He X X,Chen H,et al.The chrome-free multi-metal tanning agent ZAT and the influence of fat-liquors process[J].Leather and Chemicals,2017,34(2):21-25.
• [18] 江吉旺.无铬金属鞣剂与氨基酸的相互作用研究[D].温州:温州大学,2011.Jiang J W.Study on interaction between the chrome-free metal tanning agent[D].Wenzhou:Wenzhou University,2011.
• [19] Monica P,Maurizia S,Christian P,et al.Pilot-scale study on masking agents for titanium tanning[J].Advanced Materials Research,2015(1 120):4 081.
• [20] Zuriaga-Agustí E,Galiana-Aleixandre M V,Bes-Piá A,et al.Pollution reduction in an eco-friendly chrome-free tanning and evaluation of the biodegradation by composting of the tanned leather wastes[J].Journal of Cleaner Production,2015,87:874-881.
• [21] 高晶,李靖,廖学品,等.植物鞣剂-环氧树脂结合鞣法研究[J].中国皮革,2012,41(3):8-11.Gao J,Li J,Liao X P,et al.Combination tannage of vegetable tannin extract and epoxy resin[J].China Leather,2012,41(3):8-11.
• [22] Krishnamoorthy G,Sadulla S,Sehgal P K,et al.Greener approach to leather tanning process:d-Lysine aldehyde as novel tanning agent for chrome-free tanning[J].Journal of Cleaner Production,2013,42:277-286.
• [23] 刘伟,但年华,陈一宁,等.双醛低聚异麦芽糖的制备及其与无铬多金属结合鞣革的性能[J].中国皮革,2017,46(7):1-7.Liu W,Dan N H,Chen Y N,et al.Preparation of dialdehyde isomaltooligosaccharide and its tanning properties combined with chromium-free polymetal[J].China Leather,2017,46(7):1-7.
• [24] 马建中,侯雪艳,吕斌,等.纳米材料与技术在皮革工业中的应用[J].中国皮革,2016,45(11):29-35.Ma J Z,Hou X Y,Lv B,et al.Application of nano materials and technology in leather industry[J].China Leather,2016,45(11):29-35.
• [25] 鲍艳,杨宗邃,马建中,等.乙烯基类聚合物/蒙脱土纳米复合鞣剂与皮胶原相互作用的研究[J].中国皮革,2006,35(15):27-31.Bao Y,Yang Z S,Ma J Z,et al.Study on the interaction of vinyl polymer/montmorillonite nanocomposite tanning agents and collagen [J].China Leather,2006,35(15):27-31.
• [26] 齐梅.丙烯酸聚合物/SiO2纳米复合鞣剂的制备及应用[D].开封:河南大学,2008.Qi M.Preparation and application of acrylic polymer/SiO2 nanocomposite tanning agent[D].Kaifeng:Henan University,2008.
• [27] 雷明智,徐达宇,龙文章,等.黄牛箱包革无铬鞣生产工艺研发[J].皮革与化工,2017,34(5):28-32.Lei M Z,Xu D Y,Long W Z,et al.Research and development of chrome-free tanning production technology on cattle luggage leather [J].Leather and Chemicals,2017,34(5):28-32.
• [28] 徐达宇,刘忠卿,雷明智.黄牛箱包革无铬鞣生产技术要点[J].西部皮革,2017,39(13):55-58.Xu D Y,Liu Z Q,Lei M Z.Technical points of chrome-free tanning of cattle luggage leather [J].West Leather,2017,39(13):55-58.
• [29] 王学川,赵宇,袁旭政,等.栲胶和有机膦结合鞣制山羊服装革工艺[J].中国皮革,2009,38(21) :4-7.Wang X C,Zhao Y,Yuan X Z,et al.Combination tannage of goat garment leather by vegetable tannin extract and organic phosphonium [J].China Leather,2009,38(21) :4-7.
• [30] 梁文华,王愚.新型无铬鞣剂的应用研究[J].皮革与化工,2013,4:10-14,34.Liang W H,Wang Y.Application of a novel chrome-free tanning agent [J].Leather and Chemicals,2013,4:10-14,34.
• [31] Reineking C,Gamarino R,Trimarco L,et al.Non metal tanning[P]:US,8679196B2.2014-03-25.
• [32] Gamarino R,Trimarco L,Reineking C.Tanning process and tanning composition[P]:US,8679195B2.2014-03-25.
• [33] Reineking C,Gamarino R,Trimarco L,et al.Non-metal tanning process[P]:US,8790416B2.2014-07-29.
• [34] 赵晓东,梁文华,刘伟,等.新型环保无铬鞣剂应用工艺初探[J].中国皮革,2013,42(15):23-24.Zhao X D,Liang W H,Liu W,et al.Application of new environmental protection chrome-free tanning agent on wet-white leather pickling[J].China Leather,2013,42(15):23-24.
• [35] 陈苗苗,强西怀,陈渭,等.环保无铬鞣剂F-90与铬结合鞣制的研究[J].中国皮革,2016,45(2):32-36.Chen M M,Qiang X H,Chen W,et al.Combination tannage of chrome-free tanning agent F-90 and chrome taning agent [J].China Leather,2016,45(2):32-36.
• [36] 卢斌.F-90鞣剂对猪皮服装革的鞣制性能研究[J].皮革与化工,2017,34(3):25-29.Lu B.Tanning performance of F-90 in the pigskin garment leather [J].Leather and Chemicals,2017,34(3):25-29.
• [37] 陈苗苗.KEMIRA TANFORTMT系列鞣剂鞣制机理及其与 GranofinR Easy F-90 结合鞣制性能的研究[D].西安:陕西科技大学,2016.Chen M M.Study on the tanning mechanism of KEMIRA TANFORTMT series tanning agent and its combination with GranofinR Easy F-90 [D].Xi’an:Shaanxi University of Science & Technology,2016.
• [38] 强西怀,陈苗苗,史稼斌,等.环保高性能KEMIRA TANFORTMT系列鞣剂的性能与应用[J].中国皮革,2013,42(23):19-22.Qiang X H,Chen M M,Shi J B,et al.KEMIRA TANFORTMT-environmental and high performance tanning system [J].China Leather,2013,42(23):19-22.
• [39] Li J,Yan L,Shi B,et al.A novel approach to clean tanning technology[J].Journal of Chemistry and Chemical Engineering,2013,7(12):1 203.
• [40] 李靖,石碧,张净,等.不浸酸无铬鞣剂TWT的环保性能研究[J].西部皮革,2013,35(24):23-28.Li J,Shi B,Zhang J,et al.Study on environmental performance of non-pickling chrome-free tanning agent TWT [J].West Leather,2013,35(24):23-28.
• [41] 李靖,高晶,肖琴,等.植-无铬鞣剂TWT结合鞣法研究[J].西部皮革,2016,38(13):30-36.Li J,Gao J,Xiao Q,et al.Study on combination tannage based on vegetable tannins and chrome free tanning agent TWT [J].West Leather,2016,38(13):30-36.
• [42] 罗建勋,李靖,王诗佳,等.新型无铬鞣剂TWS在黄牛皮上的应用研究[J].中国皮革,2014,43(1):1-5.Luo J X,Li J,Wang S J,et al.Application of novel chrome-free tanning agent TWS on cattle hide [J].China Leather,2014,43(1):1-5.
• [43] Lu C,Qiang X,Li Y,et al.A cleaner method for low-chrome tanning with no-salt pickling[J].Journal of the Society of Leather Technologists and Chemists,2017,101(5):219-226.